| Oct 17, 2025 | Librelato | * | Ticona Rocabado | Round 9: Librelato, Kathie Goulart - Ticona Rocabado, Licael Roderick | ? | |
| Oct 12, 2025 | Galego | 1–0 | Librelato | Round 2: Galego, Luis - Librelato, Kathie Goulart | Ruy Lopez: Berlin Defense | |
| Sep 22, 2024 | Librelato | 0–1 | Mendoza | 45th FIDE Women's Chess Olympiad | Ruy Lopez: Morphy Defense, Classical Defense Deferred | |
| Sep 21, 2024 | Librelato | 0–1 | Sandu | 45th FIDE Women's Chess Olympiad | Bishop's Opening: Vienna Hybrid | |
| Sep 20, 2024 | Librelato | 1–0 | Rodriguez Arrieta | 45th FIDE Women's Chess Olympiad | Ruy Lopez: Closed, Breyer Defense, Zaitsev Hybrid | |
| Sep 19, 2024 | Caxita | 0–1 | Librelato | 45th FIDE Women's Chess Olympiad | Sicilian Defense: Closed, Traditional | |
| Sep 18, 2024 | Librelato | 1–0 | Zhanybekova | 45th FIDE Women's Chess Olympiad | Sicilian Defense: Taimanov Variation, Bastrikov Variation, English Attack | |
| Sep 15, 2024 | Librelato | 0–1 | Georgescu | 45th FIDE Women's Chess Olympiad | Ruy Lopez: Morphy Defense, Norwegian Variation | |
| Sep 14, 2024 | Monroy G. | 0–1 | Librelato | 45th FIDE Women's Chess Olympiad | Indian Defense: Knights Variation | |
| Sep 13, 2024 | Al Maamari | ½–½ | Librelato | 45th FIDE Women's Chess Olympiad | Zukertort Opening: Nimzo-Larsen Variation | |
| Sep 12, 2024 | Kashlinskaya | 1–0 | Librelato | 45th FIDE Women's Chess Olympiad | Semi-Slav Defense: Marshall Gambit | |
| Sep 11, 2024 | Sackie | ½–½ | Librelato | 45th FIDE Women's Chess Olympiad | Semi-Slav Defense: Accelerated Move Order | |
| May 9, 2024 | Librelato | 0–1 | Perdomo | Round 9: Librelato, Kathie Goulart - Perdomo, Leandro | Ruy Lopez: Morphy Defense | |
| May 8, 2024 | Do Valle Cardoso | 1–0 | Librelato | Round 8: Do Valle Cardoso, Lucas - Librelato, Kathie Goulart | Nimzo-Larsen Attack: Modern Variation | |
| May 7, 2024 | Flores Quillas | 1–0 | Librelato | Round 7: Flores Quillas, Diego Saul Rodri - Librelato, Kathie Goulart | Ruy Lopez: Open, Bernstein Variation | |
| May 6, 2024 | Librelato | ½–½ | Di Berardino | Round 6: Librelato, Kathie Goulart - Di Berardino, Diego Rafael | French Defense: Rubinstein Variation, Kasparov Attack | |
| May 6, 2024 | Quintiliano | 0–1 | Librelato | Round 5: Quintiliano, Renato R. - Librelato, Kathie Goulart | Catalan Opening: Open Defense | |
| May 5, 2024 | Librelato | 0–1 | Cubas | Round 4: Librelato, Kathie Goulart - Cubas, Jose Fernando | Sicilian Defense: Dragon Variation, Yugoslav Attack, Modern Line | |
| May 3, 2024 | Fier | 1–0 | Librelato | Round 3: Fier, Alexandr - Librelato, Kathie Goulart | Semi-Slav Defense: Marshall Gambit, Main Line | |
| May 2, 2024 | Librelato | 0–1 | Bachmann | Round 2: Librelato, Kathie Goulart - Bachmann, Axel | Sicilian Defense: Kan Variation, Polugaevsky Variation | |
| May 1, 2024 | Delgado Ramirez | 1–0 | Librelato | Round 1: Delgado Ramirez, Neuris - Librelato, Kathie Goulart | English Opening: Agincourt Defense | |
| Apr 28, 2024 | Labussiere | ½–½ | Librelato | Round 9: Labussiere, Yago - Librelato, Kathie Goulart | English Opening: Agincourt Defense, Catalan Defense Accepted | |
| Apr 27, 2024 | Librelato | 1–0 | Piccoli | Round 8: Librelato, Kathie Goulart - Piccoli, Lucas Fonseca | Caro-Kann Defense: Main Line | |
| Apr 27, 2024 | Librelato | 1–0 | Azevedo | Round 9: Librelato, Kathie Goulart - Azevedo, Edmundo Roberto Ramos | Scandinavian Defense: Valencian Variation | |
| Apr 27, 2024 | Librelato | 0–1 | Ribeiro | Round 7: Librelato, Kathie Goulart - Ribeiro, Matheus Mendes Domingues | French Defense: Winawer Variation, Advance Variation | |
| Apr 27, 2024 | Librelato | 0–1 | Urquiza | Round 5: Librelato, Kathie Goulart - Urquiza, Marcello de Albuquerque | Sicilian Defense: Nimzowitsch Variation, Closed Variation | |
| Apr 27, 2024 | Oliveira | ½–½ | Librelato | Round 4: Oliveira, Fernando Ventura - Librelato, Kathie Goulart | King's Indian Defense: Normal Variation, King's Knight Variation | |
| Apr 27, 2024 | Librelato | 1–0 | Lage | Round 3: Librelato, Kathie Goulart - Lage, Pedro Ferreira | Sicilian Defense | |
| Apr 27, 2024 | Guzman | 0–1 | Librelato | Round 2: Guzman, Alessandro Lucien dos S - Librelato, Kathie Goulart | East Indian Defense | |
| Apr 25, 2024 | Rangel | ½–½ | Librelato | Round 6: Rangel, Daniel - Librelato, Kathie Goulart | Semi-Slav Defense: Chigorin Defense | |
| Apr 25, 2024 | Librelato | 0–1 | Ribeiro | Round 5: Librelato, Kathie Goulart - Ribeiro, Matheus Mendes Domingues | Catalan Opening: Open Defense | |
| Apr 24, 2024 | Ribeiro | 1–0 | Librelato | Round 7: Ribeiro, Matheus Mendes Domingues - Librelato, Kathie Goulart | King's Indian Defense: Makogonov Variation | |
| Apr 24, 2024 | De Souza | 1–0 | Librelato | Round 6: De Souza, Felipe Guimaraes - Librelato, Kathie Goulart | Vienna Game: Paulsen Variation | |
| Apr 24, 2024 | Librelato | 1–0 | De Oliveira Filho | Round 5: Librelato, Kathie Goulart - De Oliveira Filho, Isac Araujo | Petrov's Defense: Three Knights Game | |
| Apr 24, 2024 | Azevedo | 0–1 | Librelato | Round 4: Azevedo, Edmundo Roberto Ramos - Librelato, Kathie Goulart | London System | |
| Apr 24, 2024 | Librelato | 0–1 | Lage | Round 3: Librelato, Kathie Goulart - Lage, Pedro Ferreira | Sicilian Defense: Four Knights Variation | |
| Apr 24, 2024 | Heubeck | 1–0 | Librelato | Round 2: Heubeck, Flavio - Librelato, Kathie Goulart | Semi-Slav Defense: Normal Variation | |
| Apr 24, 2024 | Librelato | 1–0 | Gomes | Round 1: Librelato, Kathie Goulart - Gomes, Genildo de Souza | French Defense: Classical Variation, Steinitz Variation | |
| Aug 1, 2023 | Librelato Kathie Goulart (BRA) | ½–½ | Melia Salome (GEO) | World Cup 2023 | Indian Defense: Anti-Nimzo-Indian | |
| Aug 1, 2023 | Melia Salome (GEO) | 1–0 | Librelato Kathie Goulart (BRA) | World Cup 2023 | Ruy Lopez: Morphy Defense, Modern Steinitz Defense | |
| Jul 30, 2023 | Librelato Kathie Goulart (BRA) | 1–0 | Melia Salome (GEO) | Women's World Cup 2023 | Indian Defense: Anti-Nimzo-Indian | |
| — | Melia Salome (GEO) | 1–0 | Librelato Kathie Goulart (BRA) | Women's World Cup 2023 | Ruy Lopez: Morphy Defense, Modern Steinitz Defense | |
